The oxidation of di-n-propyl-ether (DPE), was studied in a jet-stirred reactor. Mixtures with equivalence ratios from 0.5 to 4 were oxidized at a constant fuel mole fraction of 1000 ppm, at temperatures ranging from 470 to 1160 K, at 10 atm, and constant residence time of 700 ms. The mole fraction profiles were obtained through sonic probe sampling and gas chromatography and Fourier transform infrared spectrometry analyses. As was the case with diethyl ether and di-n-butyl ethers, the carbon neighboring the ether group was found to be the most favorable site for H-abstraction reactions and the chemistry of the corresponding fuel radical drives the overall reactivity. The fuel concentration profiles indicated strong low-temperature chemistry. A sub-mechanism is developed based on rules similar to those for the two symmetric ethers previously investigated (DEE and DBE).
Z. Serinyel, M. Lailliau, G. Dayma, P. Dagaut, A high pressure oxidation study of di-n-propyl ether, Fuel, 263 (2020) 116554.
